Kim Min-jae scored the first header in the 38th minute of the first half against Paris Saint-Germain at Allianz Arena in Germany.
It is his debut goal in the Champions League and his second goal this season.
Munich, who defended Kim Min-jae's first goal, beat Paris Saint-Germain 1-0.
Paris Saint-Germain's Lee Kang-in played as a substitute in the second half, but failed to raise the offensive point.
It is the first time in 13 years that a Korean player has faced off in the Champions League in the 2011-2012 season since Park Ji-sung of Manchester United and Park Joo-ho of Basel, Switzerland.
Feyenoord, where Hwang In-beom started, dropped three points against Manchester City first, but scored three goals in the second half alone, eventually drawing a draw.
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